Equilibration with Artificial Porewater

Prior to any analysis of its chemical composition, porewater has to be extracted from the rock matrix, which is not trivial in the case of low-permeability rocks such as claystones or crystalline rocks. In order to compare different extraction techniques such as aqueous extraction or squeezing, and to understand what chemical and physical processes occur during extraction, various extraction methods are applied to samples with known porewater composition. Such samples need to be prepared in the laboratory.

In an equilibration cell, a rock sample containing natural porewater is brought into contact with a small reservoir of artificial porewater of known composition. The rock sample is fully confined, allowing diffusive exchange between the two porewater reservoirs but preventing swelling. Monitoring concentration changes of major elements and added tracers such as Br in the artificial porewater reservoir over time allows determination of the time needed to attain equilibrium between porewater and external reservoir.